Closest in vocabulary probably Mexicans, who speak "post cervantino" Spanish even though some words differ substantially. In correction, probably Colombia.
Not in pronunciation though. Argentinians probably the most different together with Puerto Ricans and Dominicans and Cubans (spoken language).
I think the best place to learn is Spain, because Spanish here is like sort of the origin of all the Spanish spoken and Castillian is definitely the best. The best place in Spain is also important: Castilla y León, Madrid and CAstilla la Mancha. In other areas you might get the local language, too.
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“Aunque la conducta del marido sea censurable, aunque este se dé a otros amores, la mujer virtuosa debe reverenciarlo como a un dios. Durante la infancia, una mujer debe depender de su padre, al casarse de su marido, si este muere, de sus hijos y si no los tuviera, de su soberano. Una mujer nunca debe gobernarse a sí misma."
Leyes de Manu (Libro Sagrado de la India
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